ACID_HYDRONIUM_DISTANCE

Section to define the dissociation of a carboxylic acid in water. Distance between hydronium ion and acetate ion. Equation (2) in Supplementary Info of J. Am. Chem. Soc.,128, 2006, 11318. [Edit on GitHub]

Keywords

Keyword descriptions

HYDROGENS

Type: integer[ ]
Repeatable: yes
Usage: HYDROGENS {integer} {integer} ..

Description: Specifies indexes of atoms building the coordination variable. Hydrogens of the water molecules and of the carboxyl groups.

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LAMBDA

Type: real
Default: 2.00000000E+001
Aliases: LAMBDA
Usage: LAMBDA {real}

Description: Specifies the LAMBDA parameter carboxylic acid function.

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NC

Type: real
Default: 5.60000000E-001
Usage: NC {real}

Description: Specifies the NC parameter in the cutoff function.

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OXYGENS_ACID

Type: integer[ ]
Repeatable: yes
Usage: OXYGENS_ACID {integer} {integer} ..

Description: Specifies indexes of atoms building the coordination variable. Oxygens of the carboxyl groups.

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OXYGENS_WATER

Type: integer[ ]
Repeatable: yes
Usage: OXYGENS_WATER {integer} {integer} ..

Description: Specifies indexes of atoms building the coordination variable. Oxygens of the water molecules.

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PAOH

Type: integer
Default: 6
Usage: pAOH {integer}

Description: Sets the value of the numerator of the exponential factor in the coordination function: number of hydrogens per carboxyl group.

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PCUT

Type: integer
Default: 6
Usage: pCUT {integer}

Description: Sets the value of the numerator of the exponential factor in the cutoff function.

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PWOH

Type: integer
Default: 8
Usage: pWOH {integer}

Description: Sets the value of the numerator of the exponential factor in the coordination function: number of hydrogens per water molecule.

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QAOH

Type: integer
Default: 14
Usage: qAOH {integer}

Description: Sets the value of the denominator of the exponential factor in the coordination function: number of hydrogens per carboxyl group.

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QCUT

Type: integer
Default: 12
Usage: qCUT {integer}

Description: Sets the value of the denominator of the exponential factor in the cutoff function.

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QWOH

Type: integer
Default: 16
Usage: qWOH {integer}

Description: Sets the value of the denominator of the exponential factor in the coordination function: number of hydrogens per water molecule.

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RAOH

Type: real
Default: 2.40000000E+000 [bohr]
Usage: RAOH {real}

Description: Specify the rc parameter in the coordination function: number of hydrogens per carboxyl group.

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RWOH

Type: real
Default: 2.40000000E+000 [bohr]
Usage: RWOH {real}

Description: Specify the rc parameter in the coordination function: number of hydrogens per water molecule.

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